One mole of the complex compound Co(NH₃)₅Cl₃, gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with two moles of Ag NO₃ solution to yield two moles of AgCl(s). The structure of the complex is

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$[Co {({NH}_{3})}_{4} {Cl}_{2}] {Cl.NH}_{3}$

$[Co {({NH}_{3})}_{5} Cl] {Cl}_{2}$

$[Co {({NH}_{3})}_{4} Cl] {Cl}_{2} {.NH}_{3}$

$[Co {({NH}_{3})}_{3} {Cl}_{2}] {.2NH}_{3}$

answer is A.

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Detailed Solution

$\underset{(3 ions)}{[Co {({NH}_{3})}_{5} Cl] {Cl}_{2} \to {[Co {({NH}_{3})}_{5} Cl]}^{+ 2} + 2 {Cl}^{(-)}}$
$[Co {({NH}_{3})}_{5} Cl] {Cl}_{2} \overset{{AgNO}_{3}}{⟶} 2 AgCl ↓$

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