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Q.

One mole of the metal complex with the formula Co(en)2Cl3  gives one mole of silver chloride on treatment with an excess silver nitrate. The secondary valency of Co in the complex is ________________ .

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answer is 6.

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Detailed Solution

One mole of the metal complex with the formula Co(en)2Cl3  gives one mole of silver chloride on treatment with an excess silver nitrate

Co(en)2Cl2Cl+AgNO3 (excess) AgCl (white ppt) 

    1 mole                 1 mole             1 mole 

Since two bidentate ligands and two monodentate ligands are there, the secondary vacancy of Co in the complex is 6.

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One mole of the metal complex with the formula Co(en)2Cl3  gives one mole of silver chloride on treatment with an excess silver nitrate. The secondary valency of Co in the complex is ________________ .