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Q.

One mole of KMnO4 is used for complete oxidation of FeSO4,FeC2O4 and H2C2O4 respectively (and separately). Pick up the correct statement :

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a

5 mole of FeSO4 can be oxidised
 

b

2.5  mole of H2C2O4 can be oxidised

c


53 mole of FeC2O4 can be oxidised

d


35 mole of FeC2O4 can be oxidised

answer is A, C, D.

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Detailed Solution

The reaction is, 

(I)  KMnO+74 H+Mn+25e

(II) Fe+2+C2+3O422CO2+2+Fe+3+3e

(III)  H2C2O4 +32CO2 +4+2e

(A) 5 mole of FeSO4 can be oxidised

(B) 53 mole of FeC2O4 can be oxidised

(C) 2.5 mole of H2C2O4can be oxidised

Thus, correct options are A, C and D.

 

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