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Q.

Only iodine forms hepta-fluoride IF7, but chorine and bromine give penta-fluorides. The reason for this is:

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a

Low electron affinity of iodine.

b

That the larger iodine atom can accommodate more number of smaller fluorine atom around it.

c

Unusual pentagonal bipyramidal structure of IF7.

d

Low chemical reactivity of IF7.

answer is C.

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Detailed Solution

Iodine has the largest size among the halogens. Because of its large size, it can easily accommodate 7 fluorine atoms. Both Cl and Br have a smaller size than I, therefore if they try to accommodate 7 fluorine atoms, steric hindrance will take place. Asa result, only iodine forms IF7.

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