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Q.

Optically pure S(+)2 Bromoctane with specific rotation +360 reacts with aq. NaOH in acetone to give pure R()2 octanol with specific rotation 10.30. Partially racemized 2 – Bromoctane with specific rotation +300 on reaction with aq. NaOH produces 2 – octanol with specific rotation 60. Among the following correct statement(s) regarding second reaction is / are

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a

Optical purity of 2 – Octanol formed is nearly 58.25% 

b

Percentage of back side attack is nearly 50%

c

Optical purity of 2– Bromoctane taken is nearly 83.3% 

d

Percentage of SN2  reaction is nearly 100%

answer is A, B.

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