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Q.

Out of the two compounds shown below, the vapour pressure of II at a particular temperature is expected to be

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a

Higher than that of I 

b

Lower than that of I

c

Same as that of I

d

Can be higher or lower depending upon the size of vessel 

answer is A.

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Detailed Solution

Intramolecular H-bonding is possible in II. Therefore solubility of II will be less than I. Hence, II will be present more in vapour form compared to I.

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Out of the two compounds shown below, the vapour pressure of II at a particular temperature is expected to be