Q.

Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below.

12Cl2(g)(1/2)ΔdissHCl(g)ΔcgHCl(g)ΔhydHCl(aq)

The energy involved in the conversion of (1/2)Cl2(g) to Cl(aq) will be

Given:  Δdiss HCl2=240kJmol1;ΔcgH(Cl)=349kJmol1; and ΔhydHCl=381kJmol1

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a

152kJmol1

b

850kJmol1

c

120kJmol1

d

610kJmol1

answer is C.

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Detailed Solution

According to Hess's law

ΔH=12ΔdissH+ΔegH+ΔhydH=12(240)349381kJmol1=610kJmol1

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Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below.12Cl2(g)⟶(1/2)ΔdissH∘Cl(g)⟶ΔcgH∘Cl−(g)⟶ΔhydH∘Cl−(aq)The energy involved in the conversion of (1/2)Cl2(g) to Cl−(aq) will beGiven:  Δdiss H∘Cl2=240kJmol−1;ΔcgH∘(Cl)=−349kJmol−1; and ΔhydH∘Cl−=−381kJmol−1