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Q.

P4+3NaOH+3H2OPH3+3NaH2PO2  The equivalent mass of P4 in the above reaction is (M = Molecular weight of P4

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a

M3

b

3M2

c

M

d

M12

answer is A.

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Detailed Solution

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12e-1+P44P3

P44P3+4e-1

  4moleP412mole  e-1 gain or loss 

1 mole P4  124=3mole  e-1

Equivalent weight =M3

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P4+3NaOH+3H2O→PH3+3NaH2PO2  The equivalent mass of P4 in the above reaction is (M = Molecular weight of P4)