Q.

P4O10 react with cold water produce X (oxyacid) and P4O6 react with hot water produce Y(oxyacid) then atomicity of Y- atomicity of X =

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Detailed Solution

The reaction details are as follows:

  1. Reaction 1: P4O10 reacts with cold water:

    P4O10 + 6H2O → 4H3PO3

    • The product X is H3PO3 (phosphorous acid).
    • Atomicity of X: 7 (counting all atoms in H3PO3).
  2. Reaction 2: P4O6 reacts with hot water:

    P4O6 + 6H2O → 3H3PO4 + PH3

Atomicity Difference (Y - X): 8 - 7 = 1

Concept Behind the Reactions:

Cold Water Reaction: P4O10 reacts with cold water to form H3PO3, which is a weaker oxyacid. 
Hot Water Reaction: P4O6 reacts with hot water to form a stronger oxyacid, H3PO4, along with PH3
The difference in reactivity and products is due to the difference in oxidation states and the conditions (cold vs hot water) under which the reactions occur.

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