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Q.

Passage :

*          The order of repulsions among various electron pairs is

            lone pair – lone pair – bond pair > bond pair – bond pair

*          Presence of lone pairs at the central atom causes distortion to the regular shapes and

            deviation in bond angles.

*          Triple bonds cause more repulsions than double bonds; double bonds cause more repulsions             than single bond.  But multiple bonds between two atoms count the same as single bond.

Q. Among the following molecule having lone pair – lone pair repulsion is

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a

SF4

b

H2O

c

NH3

d

SO2

answer is A.

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Detailed Solution

Among all the given choices ,correct choice is A molecule having lone pair – lone pair repulsion is H2O

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Passage :*          The order of repulsions among various electron pairs is            lone pair – lone pair – bond pair > bond pair – bond pair*          Presence of lone pairs at the central atom causes distortion to the regular shapes and            deviation in bond angles.*          Triple bonds cause more repulsions than double bonds; double bonds cause more repulsions             than single bond.  But multiple bonds between two atoms count the same as single bond.Q. Among the following molecule having lone pair – lone pair repulsion is