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Q.

Passage of 3 Faraday of charge through aqueous solution of AgNO3, CuSO4, Al(NO3)3 and NaCl, respectively, will deposit the metals in the ratio (molar) 

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a

6 : 3 : 0 : 0 

b

3 : 2 : 1 : 0

c

1 : 2 : 3 :1 

d

6 : 3 : 2 : 6 

answer is C.

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Detailed Solution

 Ag++1e¯Ag 3F 3mole Cu+2+2e¯Cu 2F 3mole 3F32mole
In case of aq Al(NO2)3 & aq  NaCl Metal are not discharged, H+ will discharge
nAg:nCu:nAl:nNa=3:32:0:0
= 6 :3 : 0 : 0

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