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Q.

Passage :

The addition of second electron to the anion is more difficult and energy is needed to overcome the repulsion forces between negatively charged atomic sphere and the valence electron.  This energy being greater than energy released during gaining up of electron, i.e., why higher EA Values (EA2,EA3) are Endoergic nature.

A(g)+eA2(g)+eA3(g)

ΔegH=+EA2         ΔegH=EA3

i.e., EA3>EA2>EA1

EA2,EA3 are always Endoergic

EA1 Values are exoergic (however for some elements endoergic e.g. Noble gases, and alkali earth metals) while rest are endoergic.

Q.  If a student write, ΔH = +EA2here EA2 indicates

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a

Second electron gain enthalpy

b

First electron gain enthalpy

c

Third electron gain enthalpy

d

Second ionization energy

answer is B.

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Detailed Solution

If a student write, ΔH=+EA2here EA2 indicates second electron gain enthalpy.

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