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Q.

PCl5(g)  is taken in a flask at 1.0atm, sealed and allowed to attain the 
following equilibrium: 
 PCl5  PCl3+Cl2
The equilibrium mixture was then allowed to pass through a pin hole and the gases coming out of pin hole initially, was collected, analyzed and mole fraction of  Cl2 was found to be 0.53. What is the value of KP  for the dissociation of  PCl5(g)? (in bar) (Rounded off to next nearest integer)
 

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answer is 3.

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PCl5(g)  is taken in a flask at 1.0atm, sealed and allowed to attain the following equilibrium:  PCl5⇌  PCl3+Cl2The equilibrium mixture was then allowed to pass through a pin hole and the gases coming out of pin hole initially, was collected, analyzed and mole fraction of  Cl2 was found to be 0.53. What is the value of KP  for the dissociation of  PCl5(g)? (in bar) (Rounded off to next nearest integer)