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Q.

PCl5  ,  PCl3 and Cl2 are at equilibrium at 500 K and having concentration 1.6 M  PCl3, 1.6 M  Cl2 and 1.28 M PCl5 .The equilibrium constant, Kp , for the following equilibrium is
 PCl5PCl3+Cl2
[Given: R = 0.08 L.atm. mol1.K1 ]

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a

8

b

0

c

20

d

80

answer is D.

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Detailed Solution

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PCl51.28PCl31.6+Cl21.6

Kc=1.621.28=2

Kp=Kc(RT)1=2×0.08×500=80

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PCl5  ,  PCl3 and Cl2 are at equilibrium at 500 K and having concentration 1.6 M  PCl3, 1.6 M  Cl2 and 1.28 M PCl5 .The equilibrium constant, Kp , for the following equilibrium is PCl5⇌PCl3+Cl2[Given: R = 0.08 L.atm. mol−1.K−1 ]