Q.

PCl5(g) decomposes at temperature T K in to PCl3(g) and Cl2(g) according to 1st order kinetics. In a closed container initially only PCl5(g) was taken at 2atm & T K. After 12 seconds the pressure in container found to be 2.4 atm at same temperature. The rate constant (in min-1) for the decomposition of PCl5(g) at T K is _______(ln10=2.3,ln2=0.7)

 

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answer is 1.

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Detailed Solution

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K=10.2ln21.6=10.22.32.1=1min1

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