Q.

PCl5(g)PCl3(g)+Cl2(g)

In given equilibrium reaction, volume of container is inereased by mixing inert gas at constant temperature :

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a

equilibrium will shift in forward direction and concentration of Cl2(g) will decrease 

b

equilibrium will shift in backward direction and concentration of Cl2(g) will decrease

c

equilibrium will shift in forward direction and concentration of Cl2(g) will increase 

d

equilibrium will shift in backward direction and concentration of Cl2(g) will increase

answer is A.

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Detailed Solution

As V increase, equilibrium shifts in forward direction, however [Cl2]decrease because volume has increased more than increase in the moles of Cl2.

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PCl5(g)⇌PCl3(g)+Cl2(g)In given equilibrium reaction, volume of container is inereased by mixing inert gas at constant temperature :