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Q.

${[{PdBr}_{4}]}^{2 -}$ is a square planar complex. The hybridization of ${Pd}^{2 +}$ is

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a

sp³

b

dsp²

c

sp³d

d

sp³d²

answer is B.

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Detailed Solution

Protons on metal centers in [PdCl₄]^-2barely move because of their poor shielding by metal electrons the central carbon atom (C₁) receives only a tiny electric quadrupole field from this source. However, all five hydrogen atoms carry large nuclear quadrupole fields whose influence is reinforced by the weakness of the field ligand

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