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P_eq for $\large N{H_4}COON{H_{2\left( s \right)\,}} \rightleftharpoons \,2N{H_{3\left( g \right)}}\, + \,C{O_{2\left( g \right)}}\,$ at certain temperature is 0.9 atm. Then, partial pressure of ammonia at equilibrium (in atm)

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0.9

0.81

0.03

0.6

answer is D.

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Detailed Solution

$\large N{H_4}COON{H_2}\left( s \right) \rightleftharpoons 2N{H_3}\left( g \right) + C{O_2}\left( g \right)$

$\large {P_{eq}} = 0.9atm$

For every two moles of NH₃ formed, one mole of CO₂ is formed.

$\large {X_{N{H_3}}} = \frac{2}{3};{X_{C{O_2}}} = \frac{1}{3}$

$\large {P_{N{H_3}}} = \left( {\frac{2}{3} \times 0.9} \right)atm$

$\large \boxed{{P_{N{H_3}}} = 0.6atm}$

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