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Percentage yield of ${SO}_{3}$ in the following reaction is plotted against pressure at definite
temperatures. ${2SO}_{2 (g)} {+ O}_{2 (g)} ⇌ {2SO}_{3 (g)};$ which of the following reaction is correct?

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$T_{1} {> T}_{2} {> T}_{3}$

$T_{3} {> T}_{2} {> T}_{1}$

$P_{1} {< P}_{2} {< P}_{3}$

$P_{3} {< P}_{2} {< P}_{1}$

answer is A.

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Detailed Solution

${SO}_{2} {+ O}_{2} ⇌ {2SO}_{3} is exothermic$

$∴ as T ↑, % yield ↓$

$∴ T_{1} {> T}_{2} {> T}_{3}$

$and as P ↑, % yeild ↑$

$∴ P_{3} {> P}_{2} {> P}_{1}$

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