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Q.

Phenol can be prepared by the reaction between

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a

Aniline and HNO2 at 373 K

b

C6H5MgBr and CO2 followed by hydrolysis

c

C6H5Cl and NaOH at 373 K

d

C6H5SO3Na and NaOH at 573–623K followed by acidification

answer is D.

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Detailed Solution

Given data:It is given to identify from which reagents phenol can be prepared.

Explanation:

Phenol is the end product of the reaction between chlorobenzene and solid NaOH. . Here, the chlorobenzene's chlorine ion is replaced by the hydroxide ion, resulting in the production of phenol. But this reaction occurs at 623K

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Hence, correct option is: (D) C6H5SO3Na and NaOH at 523 -623K followed by acidification

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