Q.

Phenol on treatment with CO2 in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with (CH3CO)2O in the presence of catalytic amount of H2SO4 produces : 

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a

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b

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c

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d

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answer is A.

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Detailed Solution

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The very first reaction in the above road map looks like Kolbe’s reaction which results to salicylic acid as : 

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The salicylic acid with acetic anhydride [(CH3CO)2O] in the presence of catalytic amount of conc. H2SO4 undergoes acylation to produce aspirin as: 

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Aspirin is a non-narcotic analgesic (pain killer). 

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