Q.

 Phenol  conc. H2SO4A conc. HNO3B
Here A and B are respectively

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a

4–Hydroxybenzene–1,3–disulphonic acid, picric acid

b

P–Hydroxy benzenesulphonic acid, P–nitrophenol

c

4–Hydroxybenzene-1,3–disulphonic acid, 2,4–dinitrophenol

d

3–Hydroxybenzenesulphonic acid, picric acid

answer is B.

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Detailed Solution

Sulphonation is a reversible process, henece at high temperature SO3H groups are lost and nitration will occur.

If we treat phenol with conc H2so4 It will give what - Chemistry - Alcohols  Phenols and Ethers - 10188523 | Meritnation.com
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 Phenol ⟶ conc. H2SO4A⟶ conc. HNO3BHere A and B are respectively