Q.

pH of 0.05 M Ammonium formate solution at 298 K is 6.93. pH of 0.01M Ammonium formate solution at the same temperature would be

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a

7

b

6.96

c

6.93

d

7.02

answer is B.

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Detailed Solution

HCOONH4 is a salt of  WA - WB

pH of salt of WA-WB is independent of concentration of the salt.

pH of salt of WA-WB depends on Ka of weak acid and Kb of weak base only.

pH=7 + 12pKa -  12pKb

Thus pH remains 6.93

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