Q.

pH of 0.05 M Ammonium formate solution at 298 K  is 6.93. pH of 0.01M  Ammonium formate solution at the same temperature would be

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a

7

b

6.96

c

6.93

d

7.02

answer is B.

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Detailed Solution

HCOONH4 is a salt of WA-WB.

pH of a salt of WA- WB  is independent of concentration of the salt.

pH of a salt of WA-WB depends on Ka of  weak acid and Kb of weak base only.

pH=7+12pKa-12pKb;

Thus pHremains 6.93 ;

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