Q.

pH of the mixture containing 200ml of 0.1M CH3COOH and 100ml of 0.15M KOH is pka of  CH3COOH=4.8

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a

4.8

b

4.8+log2

c

4.8-log5

d

4.8+log3

answer is D.

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Detailed Solution

Number of milli equivalents of CH3COOH = 200(0.1M)1 = 20

Number of milli equivalents of KOH = 100(0.15M)1 = 15

Excess WA + limited SB acts like an acidic buffer

WA15  meq20  meq5  meqexcess + SB15  meq  salt15  meq + water  

The solution contains 5 meq of WA and  15 meq of Salt. 

pH=pka+logVsNsVaNapH=4.8+log155pH=4.8+log3

 

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