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Q.

Photochemical fluorination is explosive, while iodination is too slow to occur. The reason for this

is

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a

Bond dissociation energy of I2 is minimum

b

Formation of CH3-F is most exothermic 

c

Formation of HF is exothermic and that of HI is endothermic. 

d

F2 has lower bond dissociation energy than I2

answer is B.

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Detailed Solution

Due to the low bond dissociation energy of F2, the fluorination of hydrocarbons with pure fluorine gas occurs explosive and releases a large amount of heat.

Whereas, high bond dissociation energy of I2, the iodination of hydrocarbons requires a large amount of heat.

Therefore, formation of CH3-F and HF is exothermic whereas that of HI is endothermic. 

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