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Q.

Pick out the incorrect statement

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a

N2 has greater dissociation energy than N2+..

b

O2 has lower dissociation energy than O2+.

c

Bond length in N2+is less than N2.

 

d

Bond length in NO+is less than in  NO.

answer is C.

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Detailed Solution

One electron is lost from both N2+ and O2+, causing a drop in bond strength and an increase in bond dissociation energy compared to N2 and O2.
An organism's species' bond order and length are inversely related.

N2

Total valence electrons are equal to 10 ((5+5)).
As a result, its electronic configuration is (σ2s)2(σ2s*)2(σ2px)2(π2py,π2pz)2(σ2px*)(π2py*,π2*pz)
signifies anti bonding electrons.
Bond order formula is represented by;
Bond order is calculated as follows: Bond order (8-2)/2=3 (Number of Bonding Electrons - Number of Antibonding Electrons)

means anti bonding electrons

Bond order formula can be written as;

Bond order =( Number of Bonding electrons - Number of antibonding electrons )2N2+

Total valence electron =(5+51)=9 is present.
This means that its electrical arrangement is

(σ2s)2(σ2s*)2(σ2px)2(π2py2,π2pz1)(σ2px*)(π2*py,π2pz*)

Bond order  (7-2)2=2.5

Bond Order 3 and N 2
The bond order of N2+ is 2.5. Therefore, N2 will have a longer bond length than N2+.

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