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Q.

Pick out the incorrect statement among the following 

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a

If the change in volume of an ideal gas system is zero then the work done by the gas is always zero

b

The specific heat of an ideal gas can be negative

c

Change in internal energy of an ideal gas in isothermal process is zero

d

In adiabatic expansion of ideal gas the internal energy of the gas decreases

answer is A.

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Detailed Solution

1.  In a cyclic process the change in volume is zero but work done is not zero so (1) is incorrect statement.
2.  For a gas which obey’s  PVx=constant
C=Rγ1+R1x
We can see that x can have a range of values, which can make  C  negative. Hence it is correct.
3. dU=nCvdT , for an isothermal process, change in temperature is zero, hence there will be no change in internal energy.
4. Using first law of thermodynamics dQ=dU+dW , for adiabatic process  dQ=0
Hence,  dU=dW. Therefore, during expansion work done is positive, the internal energy decreases.
Therefore, the correct answer is  A
 

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