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Q.

pK1 and pK2 of H2CO3 are respectively 6.38 and 10.26. pH of 1 M and 0.1 M NaHCO3 respectively are

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a

8.32, 7.32 

b

7.32, 8.32

c

8.32, 8.32

d

7.32, 7.32

answer is C.

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Detailed Solution

H2​CO3​+H2​O⇌HCO3−​+H3​O+; pK1​=6.38
HCO3−​+H2​O⇌CO32−​+H3​O+; pK2​=10.26

HCO3- is proton acceptor as well as proton donor and therefore it is amphiprotic,

pH=pK1+pK22=8.32

As pH in indendepndent of concentration, therefore value of both 1 M and 0.1 M NaHCO3 is 8.32.

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