Q.

Plotting 1/m against cm for aqueous solutions of a monobasic weak acid (HX) resulted in a straight line with y-axis intercept of  P and slope of  S. The ratio P / S is
m= Molar conductivity of  HX at concentration 'C'.

m = Limiting molar conductivity of  HX.
c = Molar concentration of  HX.
ka  = Dissociation constant of Hx]

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a

1/(Kam)

b

Kam/2

c

2Kam

d

Kam

answer is A.

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Detailed Solution

For weak acid,   Question Image

Question Image
Divide by  'm'
  Question Image
Plot Question Image has  slope  Question Image y-intercept =10 = P Then, Question Image

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