Q.

Poor shielding of nuclear charge by d or f-orbital elements is responsible for which of the following facts?

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a

Atomic radius of Nb(4-d series) is comparable to that of Ta(5-d series).

b

The 1st ionisation energy of copper is leas than that of zinc.

c

The value of electron gain enthalpy is more negative for sulphur than for oxygen.

d

The 1st ionisation energy for gold is greater than that of silver.

answer is A, D.

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Detailed Solution

The nucleus charge is not well-shielded by the d and f orbitals. Therefore, right after the d or f orbitals have been fully filled, there is a considerable reduction in the size of the ions. The term for this is lanthanide contraction. Due to lanthanide contraction, the atomic radii of NbNb3+=0.72A˙ and TaTa3+=0.72 are practically similar. This explains why gold has a higher ionisation energy than silver.

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