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Q.

Predict the product of the reaction of 1-pentyne and excess of HCl in the presence of hydrogen peroxide.

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a

1,1-dichloropentane

b

1,2-dichloropentane

c

2,2-dichloropentane

d

2-chloro-I-pentane

answer is C.

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Detailed Solution

Question Image

HCI and HI in peroxide follow Markovnikov's rule whereas with HBr in peroxide, follow anti Markovnikov's addition.

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