Predict which of the following reaction will have appreciable concentration of reactants and products?

${\mathrm{Cl}}_2\left(\mathrm{g}\right)\rightleftharpoons 2\mathrm{Cl}\left(\mathrm{g}\right);{\mathrm{K}}_{\mathrm{C}}=5\times {10}^{-39}$

${\mathrm{Cl}}_2\left(\mathrm{g}\right)+2\mathrm{NO}\left(\mathrm{g}\right)\rightleftharpoons 2\mathrm{NOCl}\left(\mathrm{g}\right);{\mathrm{K}}_{\mathrm{C}}=3.7\times {10}^8$

${\mathrm{Cl}}_2\left(\mathrm{g}\right)+ 2\mathrm{NO}\left(\mathrm{g}\right) \rightleftharpoons 2\mathrm{NOCl}\left(\mathrm{g}\right) ; {\mathrm{K}}_{\mathrm{C}}=1.8$

All have appreciable concentration of reactants and products