Predict which of the following reaction will have appreciable concentration of  reactants and products:

${\text{Cl}}_{\text{2}}\text{ (g) }\stackrel{ }{\rightleftharpoons }{\text{ 2Cl (g) K}}_{\text{C}}\text{ = 5}\times {\text{ 10}}^{\text{-39}}$

${\text{Cl}}_{\text{2}}\text{ (g) + 2NO (g)}\stackrel{ }{\rightleftharpoons }{\text{ 2NOCl (g) K}}_{\text{C}}\text{ = 3.7}\times {\text{10}}^{\text{8}}$

${\text{Cl}}_{\text{2}}{\text{ (g) + 2NO}}_{\text{2}}\text{ (g) }\stackrel{ }{\rightleftharpoons }{\text{ 2NO}}_{\text{2}}{\text{Cl (g), K}}_{\text{C}}\text{ = 1.8}$

${\text{H}}_{\text{2}}{\text{(g) + Cl}}_{\text{2}}\text{ (g) }\stackrel{ }{\rightleftharpoons }{\text{ 2HCl (g), K}}_{\text{C}}\text{ = 4}\times {\text{10}}^{\text{31}}$