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Q.

Preparation of a compound X leads to a mixture with 20% racemization and 80% retention. What should be the observed rotation of the mixture, if [α]D=12?

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a

+2.4°

b

- 9.6°

c

+ 9.6°

d

-2.4°

answer is B.

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Detailed Solution

αobs. =% retention × specific rotation αobs. =0.8012=9.6

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