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Q.

Presence of aldehyde group in glucose is indicated by its reaction with

A) Br2/H2O

B) Tollen's reagent

C) Fehling's reagent

D) conc.HNO3

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a

A, B, C, D

b

A, B, C only

c

 B, C, D only

d

 B, C only

answer is B.

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Detailed Solution

Aldehyde group is very much susceptible to oxidation;

A,B,C are mild oxidizing agents;

They oxidize glucose to gluconic acid;

Question Image

They cannot oxidize primary alcohol group;

Concentrated nitric acid not only oxidizes aldehyde group-CHO to  -COOH group but oxidizes primary alcohol group-CH2OH also to -COOH  group;

It is thus useful to detect the presence of primary alcohol groupCH2OH in glucose ;

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