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Q.

Pressure necessary to obtain 50% dissociation of PCl5 for PCl5PCl3+Cl2 at 500K will be equal to

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a

2Kp

b

4Kp

c

3Kp

d

Kp

answer is C.

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Detailed Solution

If P is the total required pressure, then 
PPCl5=0.51.5×P=P3, PPCl3=0.51.5×P=P3, PCl2=0.51.5×P=P3, Kp=PPCl3×PCl2PPCl5=3P  P=3Kp

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