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Q.

Primary amines have lower boiling points than

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a

corresponding alkanes

b

corresponding esters

c

corresponding alcohols

d

corresponding 2o and 3o amines

answer is D.

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Detailed Solution

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Amines generally have lower boiling points than alcohols of comparable molar mass because amines have weaker hydrogen bonds than alcohols. Consider the compounds methanol and methylamine. Methanol has strong hydrogen bonds.

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