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Q.

Propane reacts with chlorine in sunlight to give two products. 1-chloropropane is obtained in 44% yield and 2-chloropropane is obtained in 56% yield of the total product. What will be the percent yield of the major product obtained when butane is treated with CI2 in similar conditions. (Round answer as nearest integer)

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answer is 72.

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Detailed Solution

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Reactivity of 2° & 1° H =3.8:1

Reactive of 1°H = 6×1 =6

Reactive of 2°H=3.8×4=15.2

                                             Total=21.2

Amount of primary product =621.2×100=28.30

Amount of secondary product =15.221.2×100=71.772

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Propane reacts with chlorine in sunlight to give two products. 1-chloropropane is obtained in 44% yield and 2-chloropropane is obtained in 56% yield of the total product. What will be the percent yield of the major product obtained when butane is treated with CI2 in similar conditions. (Round answer as nearest integer)