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Q.

Propanone reacts with iodine in acid solution as shown in this equation.

CH3C(O)CH3+I2H+CH3C(O)CH2I+HI

These data were obtained when the reaction was studied

CH8C(O)CH8,Ma2,MB+,MRelative Rate
0.0100.0100.0101
0.0200.0100.0102
0.0200.0200.0103
0.0200.0100.0204

What is the rate equation for the reaction?

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a

Rate =kCH3C(O)CH3I2

b

Rate =kCH3C(O)CH3I2H+

c

Rate =kCH3C(O)CH32

d

Rate =kCH3C(O)CH3H+

answer is D.

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Detailed Solution

n=0 m=1

42=0.010.02n0.020.01P42=22=2p=1

Rate  =kCH3CCCH3H+

option D.

 rate =KCn3inmILnx+P (1)  1=k(0.01)m(0.01)n(0.01)p (2)  z=k(0.02)m(0.01)n(0.01)p (3)  2=k(0.02)m(0.02)n(0.01)p4=k(0.02)m(0.01)n(0.02)p taking iohto (2)/(1) 21=0.020.01m0.010.01n0.010.012=2mm=1 taking satio (3) (2) 22=0.020.01n1=2nn=0

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