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Q.

Propene reacts HCl to form ‘P’ (major product). Propene reacts with HCl in presence of Benzoyl peroxide to form ‘Q’ (major product). P and Q are

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a

(CH3)2CHCl,CH3CH2CH2Cl

b

(CH3)2CHCl,(CH3)2CHCl

c

CH3CH2CH2Cl,CH3CH2CH2Cl

d

CH3CH2CH2Cl,(CH3)2CHCl

answer is A.

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Detailed Solution

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HCl cannot be broken to free radicals by a peroxide.   

HCl even in presence of peroxide gives Markonikoff’s product (Electrophilic addition product).

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