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Q.

Property of transition element
1) Color of ion
2) Variable oxidation states
3) Formation of alloys
4) Paramagnetic
Reason for the property
A) unpaired e- in (n-1)d orbital
B) same crystal structure
C) d-d- transition
D) high magnitude of positive charge
E) slight energy between ns and (n–1)d shells
The correct match is

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a

1-C, 2-E, 3-A, 4-B

b

1-C, 2-E, 3-B, 4-A

c

1-C, 2-B, 3-E, 4-A

d

1-B, 2-A, 3-E, 4-B

answer is B.

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Detailed Solution

  • The color of the coordination complexes is due to the d-d transition takes place in the complexes.
  • Metals of the coordination complexes are transition metals and they shows variable oxidation states because there is very less energy difference between ns and (n-1)d subshells.
  • Transition metals has a very less difference in their atomic sizes, thereby one metal easily replaced by another metal from its lattice for the formation of an alloy.
  • Paramagnetic nature is due to the presence of unpaired electrons in the outermost d subshell.
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