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Q.

Pt|Cl2(P1)|HCl(0.1M)|Pt|Cl2(P2); cell reaction will be spontaneous if: 

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a

P1>P2

b

P1=P2=1 atm

c

P1=P2

d

P2>P1

answer is C.

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Detailed Solution

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Ecell=Ecell0-RT1FlnP2P112 Ecell0=EC0-Ea0=0-0=0 Ecell=RTFlnP1P212 Ecell=RT2FlnP1P2 P1>P2Ecell=+ve               G=-ve Spontaneous cell reaction.

OR 

G = -2.303RTlogK G = -2.303RTlogP1P2 If P1>P2 G = -ve Spontaneous.

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