Banner 0
Banner 1
Banner 2
Banner 3
Banner 4
Banner 5
Banner 6
Banner 7
Banner 8
Banner 9

Q.

Pt(Ox)( py )2O2H2O Select correct statement about this complex :

see full answer

Your Exam Success, Personally Taken Care Of

1:1 expert mentors customize learning to your strength and weaknesses – so you score higher in school , IIT JEE and NEET entrance exams.
An Intiative by Sri Chaitanya

a

Oxidation state of O2 is -1

b

EAN of Pt is 86

c

Complex will show geometrical as well as optical isomerism

d

Both (b) and (c)

answer is D.

(Unlock A.I Detailed Solution for FREE)

Best Courses for You

JEE

JEE

NEET

NEET

Foundation JEE

Foundation JEE

Foundation NEET

Foundation NEET

CBSE

CBSE

Detailed Solution

The nearest inert gas of Pt is Rn, the total electrons in Rn is 86. By calculating the EAN of Pt in the complex, Pt(ox)py2O2H2O. EAN =ZON+(2×L) Where, Z is atomic number, ON is oxidation state on central metal, and L is ligand.

Pt=ZON+(2×L)=784+(2×6)=86Ox is a bidentate complex with an octahedral structure in this complex. So there are two types of geometrical isomerism possible here: cis and trans. It may also exhibit optical isomerism due to its less symmetric nature.

So, option D is correct.

Watch 3-min video & get full concept clarity
score_test_img

courses

No courses found

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Get Expert Academic Guidance – Connect with a Counselor Today!

best study material, now at your finger tips!

  • promsvg

    live classes

  • promsvg

    progress tracking

  • promsvg

    24x7 mentored guidance

  • promsvg

    study plan analysis

download the app

gplay
mentor

Download the App

gplay
whats app icon
personalised 1:1 online tutoring