Pure water freezes at 273K and 1bar and boils at 373K and 1 bar. Addition of non-volatile solute changes the freezing  and boiling point of water. Boiling point of an aqueous solution is 100.56⁰C. Latent heat of fusion and latent heat of vaporization of water are  ${\text{ 80 Cal.g }}^{-1}\text{ and }540 \mathrm{Cal}.{\mathrm{g}}^{-1}$ respectively. The figures shown below represent plot of
vapour pressure (V.P) versus temperature (T). Identify the correct plot.