Q.

 R-CNLiAlH4Q

R-CNRMgX+H2O/H+P

the products P and Q are respectively

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a

1° - alcohol and 1° - amine

b

ketone and 1° - amine

c

aldehyde and 1° - alcohol

d

 2° - alcohol and 1° - amine

answer is B.

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Detailed Solution

The products P and Q are Ketone and 1 amine respectively. 

  • Alkyl cyanide reacts with Grignard reagent (followed by acid hydrolysis) to form a ketone. 
  • Alkyl cyanide on reduction with lithium aluminum hydride forms primary amine. Following is the reaction that takes place;

               R-CN+LiAlH4R-CH2-NH2(amine)

Hence, the correct answer is B) ketone and 1° - amine

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 R-C≡N→LiAlH4QR-C≡N→RMgX+H2O/H+Pthe products P and Q are respectively