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Q.

R-I : NH3+BF3    H3NBF3

R-II : NH3+H+ NH4+

Correct statements about R-I and R-II are

A) NH3 is a Lewis base in both R-I and R-II

B) NH3 is a Bronsted-Lowry base in both R-I and R-II

C) NH3 is a Lewis base only in R-I

D) NH3 is a Lewis base only in R-II

E) NH3 is a Bronsted-Lowry base only in R-II

F) NH3 is a Bronsted-Lowry base only in R-I

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a

A, B, C, D, E, F

b

A, E only

c

A, C, D, F only

d

B, D only

answer is B.

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Detailed Solution

I) In R-I…. N..H3 donates lone pair to BF3 and thus acts like Lewis base. In this reaction NH3 is not a proton acceptor. It is not a Bronsted Lowry base

II) In R-II… N..H3 donates lone pair to H+ (proton) ;

It is an electron pair donor and a proton acceptor.Thus it acts like Lewis base and a Bronsted-Lowry base.

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