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Q.

Radii of A+ and that of X- and Y- have been given as A+= 1.00 pm, X- =1.00 pm, Y- = 2.00 pm.
Thus, ratio of volumes of AX and AY unit cells is

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a

17.54

b

1.0

c

0.217

d

0.057

answer is C.

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Detailed Solution

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Ratio of r+/r_ will decide the type of unit cell.

For AXrA+rX=11=1.0 hence, AX has bcc structure. 

2rA++rX=a3a=23rA++rX=2×23=43PM

 Volume (AX)=a3=433=6433 For AY rA+rY=12=0.5

Thus, octahedral or square planar structure.

r=a2

a=2r=2rA++rY=2(1+2)=6pm  Volume (AY)=a3=216pm3  Ratio = Volume (AX) Volume (AY)=6433×216=0.057

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