Q.

Rank the following species in order of decreasing nucleophilicity in a polar protic solvent (most least nucleophilic) :

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a

2>1>3

b

3>1>2

c

1>3>2

d

2>3>1

answer is D.

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Detailed Solution

In polar protic solvent, less hydrogen bonding nucleophile is more nucleophilic.

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Rank the following species in order of decreasing nucleophilicity in a polar protic solvent (most →least nucleophilic) :