Q.

Rate law for substitution reaction of 2-bromobutane with OHΘ in 75% ethanol and 25% water at 300C is rate =3.20×105 (2-bromobutane) [OH]+1.5×106 (2-bromobutane) what percent of reaction take place by SN2 when [OH]=1.00M ? (Answer must be in nearest whole number)

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answer is 95.

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Detailed Solution

%by ​ SN2=SN2SN2+SN1×100  =3.20×105[2bromobutane][1.00]×1003.20×105[2bromobutane][1.00]+1.5×106[2bromobutane] =3.20×1053.20×105+0.15×105×100=95to96%

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